Dual resistance heater for phase change devices and manufacturing method thereof

ABSTRACT

A dual resistance heater for a phase change material region is formed by depositing a resistive material. The heater material is then exposed to an implantation or plasma which increases the resistance of the surface of the heater material relative to the remainder of the heater material. As a result, the portion of the heater material approximate to the phase change material region is a highly effective heater because of its high resistance, but the bulk of the heater material is not as resistive and, thus, does not increase the voltage drop and the current usage of the device.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No.11/312,231, filed Dec. 19, 2005, which claims the benefit of EP04107070.7, filed Dec. 30, 2004, the entire contents of which are herebyincorporated by reference herein.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a dual resistance heater for phase changedevices and to the manufacturing method thereof. In particular, theinvention relates to a heater for phase change memory devices.

2. Description of the Related Art

Phase change memory devices use phase change materials, i.e., materialsthat may be electrically switched between a generally amorphous and agenerally crystalline state, for electronic memory application. One typeof memory element utilizes a phase change material that is electricallyswitched between a structural state of generally amorphous and generallycrystalline local order or between different detectable states of localorder across the entire spectrum between completely amorphous andcompletely crystalline states. The state of the phase change materialsis also non-volatile in that, when set in either a crystalline,semi-crystalline, amorphous, or semi-amorphous state representing aresistance value, that value is retained until changed by anotherprogramming event, as that value represents a phase or physical state ofthe material (e.g., crystalline or amorphous). The state is unaffectedby removing electrical power.

Turning to FIG. 1, an embodiment of a memory 100 is illustrated. Memory100 includes a n×n array of memory cells 111-119, wherein memory cells111-119 each include a select device 120 and a memory element 130.

Memory elements 130 comprise a phase change material, thus memory 100may be referred to as a phase change memory. A phase change material isa material having electrical properties (e.g., resistance, capacitance,etc.} that may be changed through the application of energy such as, forexample, heat, light, voltage potential, or electrical current. Examplesof a phase change material include a chalcogenide material.

A chalcogenide alloy may be used in a memory element or in an electronicswitch. A chalcogenide material is a material that includes at least oneelement from column VI of the periodic table or is a material thatincludes one or more of the chalcogenic elements, e.g., any of theelements of tellurium, sulfur, or selenium.

Memory 100 includes column lines 141-143 and row lines 151-153 to selecta particular memory cell of the array during a write or read operation.Column lines 141-143 and row lines 151-153 may also be referred to asaddress lines since these lines may be used to address memory cells111-119 during programming or reading. Column lines 141-143 may also bereferred to as bit lines and row lines 151-153 may also be referred toas word lines.

Memory elements 130 are connected to row lines 151-153 and are coupledto column lines 141-143 via select device 120. While one select device120 is depicted, more select devices may also be used. Therefore, when aparticular memory cell (e.g., memory cell 115) is selected, voltagepotentials may be applied to the memory cell's associated column line(e.g., 142) and row line (e.g., 152) to apply a voltage potential acrossthe memory cell.

Series connected select device 120 is used to access memory element 130during programming or reading of memory element 130. The select device120 is an ovonic threshold switch that is made of a chalcogenide alloythat does not exhibit an amorphous to crystalline phase change and whichundergoes rapid, electric field initiated change in electricalconductivity that persists only so long as a holding voltage is present.Select device 120 operates as a switch that is either “off” or “on”depending on the amount of voltage potential applied across the memorycell, and more particularly whether the current through the selectdevice exceeds its threshold current or voltage, which then triggers thedevice into the on state. The off state is a substantially electricallynonconductive state and the on state is a substantially conductivestate, with less resistance than the off state. In the on state, thevoltage across the select device is equal to its holding voltage V_(H)plus I×R_(on), where R_(on) is the dynamic resistance from V_(H). Forexample, select device 120 has a threshold voltage and, if a voltagepotential less than the threshold voltage of a select device 120 isapplied across select device 120, then the select device 120 remains“off” or in a relatively high resistive state so that little or noelectrical current passes through the memory cell and most of thevoltage drop from selected row to selected column is across the selectdevice. Alternatively, if a voltage potential greater than the thresholdvoltage of select device 120 is applied across select device 120, thenthe select device 120 “turns on,” i.e., operates in a relatively lowresistive state so that electrical current passes through the memorycell. In other words, select device 120 is in a substantiallyelectrically nonconductive state if less than a predetermined voltagepotential, e.g., the threshold voltage, is applied across select device120. Select device 120 is in a substantially conductive state if greaterthan the predetermined voltage potential is applied across select device120. Select device 120 may also be referred to as an access device, anisolation device, or a switch.

Here, each select device 120 comprises a switching material such as, forexample, a chalcogenide alloy, and may be referred to as an ovonicthreshold switch, or simply an ovonic switch. The switching material ofselect device 120 is a material in a substantially amorphous statepositioned between two electrodes that may be repeatedly and reversiblyswitched between a higher resistance “off” state (e.g., greater thanabout ten megaOhms) and a relatively lower resistance “on” state (e.g.,about one thousand Ohms in series with V_(H)) by application of apredetermined electrical current or voltage potential. Here, each selectdevice 120 is a two terminal device that has a current-voltage (I-V)characteristic similar to a phase change memory element that is in theamorphous state. However, unlike a phase change memory element, theswitching material of select device 120 does not change phase. That is,the switching material of select device 120 is not a programmablematerial, and, as a result, select device 120 is not a memory devicecapable of storing information. For example, the switching material ofselect device 120 remains permanently amorphous and the I-Vcharacteristic remains the same throughout the operating life. Arepresentative example of I-V characteristics of select device 120 isshown in FIG. 2.

In FIG. 2, in the low voltage or low electric field mode, i.e., wherethe voltage applied across select device 120 is less than a thresholdvoltage (labeled V_(TH)), select device 120 is “off” or nonconducting,and exhibits a relatively high resistance, e.g., greater than about 10megaOhms. Select device 120 remains in the off state until a sufficientvoltage, e.g., V_(TH), is applied, or a sufficient current is applied,e.g., I_(TH), that switches select device 120 to a conductive,relatively low resistance on state. After a voltage potential greaterthan about V_(TH) is applied across select device 120, the voltagepotential across select device 120 drops (“snapback”) to a holdingvoltage potential, labeled V_(H). Snapback refers to the voltagedifference between V_(TH) and V_(H) of a select device.

In the on state, the voltage potential across select device 120 remainsclose to the holding voltage V_(H) as current passing through selectdevice 120 is increased. Select device 120 remains on until the currentthrough select device 120 drops below a holding current, labeled I_(H).Below this value, select device 120 turns off and returns to arelatively high resistance, nonconductive off state until the V_(TH) andI_(TH) are exceeded again.

In known phase change memory cells, there is the problem that relativelyhigh levels of currents are required to switch the phase change materialof the memory elements.

Another disadvantage of known change memory cells resides in the pooradhesion of the chalcogenide material to the underlying heater,resulting in some instances in a delamination of patterned electrodestacks.

The same problem affects all devices including a phase change materiallayer overlying a resistive heater.

BRIEF SUMMARY OF THE INVENTION

In one embodiment, the present invention provides a device including aphase change layer that requires less current for causing switching ofthe phase change layer. In particular, the device comprises a phasechange material region and a heater, the heater having a surface regionin contact with said phase change material region, wherein the surfaceregion has a higher resistance than that of another portion of saidheater.

In another embodiment, a method for manufacturing a phase change deviceis described, the method comprising forming a heater and increasing theresistance of a surface of the heater by ion implantation of silicon oroxygen ion.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWING(S)

For the understanding of the present invention, preferred embodimentsare now described, purely as a non-limitative example, with reference tothe enclosed drawings, wherein:

FIG. 1 is a schematic diagram illustrating a phase change memory;

FIG. 2 is a diagram illustrating a current-voltage characteristic of anaccess device of the phase change memory of FIG. 1;

FIG. 3 is an enlarged cross-sectional view of one embodiment of thepresent invention;

FIGS. 4-13 are enlarged cross-sectional views of the embodiment shown inFIG. 3 at subsequent stages of manufacture in accordance with oneembodiment of the present invention;

FIG. 14 is a schematic system depiction of one embodiment of the presentinvention;

FIGS. 15-21 are enlarged cross-sectional views of another embodiment ofthe present invention at subsequent stages of manufacture.

DETAILED DESCRIPTION OF THE INVENTION

Referring to FIG. 3, a phase change memory cell, such as a cell 111-119in FIG. 1, is formed in a substrate 10. Over the substrate 10 variousinterconnections and transistor features are formed. An interlayerdielectric 12 separates those features from the features provided abovethe interlayer dielectric 12. A conductor 14 extends above theinterlayer dielectric 12 and act as a row line 151-153 (FIG. 1). At thetop, a conductor 36 extends generally transversely to the electrode 14and acts as a column line 141-143 (FIG. 1).

A dielectric layer 16 has a pore formed therein and the poreaccommodates a spacer 22, a lance heater 24, and a phase change memorymaterial 28 which, together with the heater 24, form a phase changememory element 130 (FIG. 1). A region 26 of the heater 24 has a higherresistance than the region 27. Thus, the heater 24 is a dual resistanceheater made up of the region 26 and the region 27, each region having adifferent resistance, although both regions may be formed of the samestarting material. The region 27 has a lower resistance, so it creates alower voltage drop, reducing the power consumed by the heater 24 and,thus, the cell as a whole.

An ovonic threshold device 120 (FIG. 1) is formed above the phase changememory material 28 and acts as a selection or threshold device for theunderlying memory element 130. The ovonic threshold device 120 is formedin a dielectric layer 18, e.g., of nitride, and in a dielectric layer20, e.g., oxide. The threshold device 120 includes a lower electrode 30,an upper electrode 34, a surrounding dielectric layer 38, and aswitching material 32. The switching material 32 may, like the memorymaterial 28, be a chalcogenide. However, generally, the switchingmaterial 32 does not change phase.

The formation of the cell shown in FIG. 3 begins with the formation of acontact or lance opening 17 in the dielectric 16, as shown in FIG. 4.The dielectric 16 is, e.g., of oxide.

Next, as shown in FIG. 5, a sidewall spacer 22 is formed in the opening17. The sidewall spacer 22 may be formed by conventional techniques,including the deposition of a layer of nitride followed by anisotropicetching.

Then, FIG. 6, a heater 24 is deposited to fill the opening 17. Theheater 24 may, for example, be titanium nitride.

The heater 24 is recessed to create the recess 25 shown in FIG. 7. Theheater 24 is planarized prior to being recessed. The recess 25 may becreated by dry or wet etching processes known as dip backs or etchbacks. Thereafter, the exposed structure is subjected to an ionimplantation indicated as A in FIG. 7. E.g., the ion implantation may bean implantation of silicon at 20 keV and 1015 atoms per squarecentimeter.

A result of the implant is to convert at least an upper region 26 of theheater 24 into a higher resistance state. For example, where the heater24 is titanium nitride, the upper region 26, shown in FIG. 8, becomestitanium silicon nitride as a result of an implant followed by aneffective anneal while the remaining region 27 remains titanium nitride.The titanium silicon nitride in the region 26 has a higher resistancethan the underlying material in the region 27.

Thus, FIG. 8, the upper region 26 of the heater 24 has a higherresistance than the region 27. Preferably, the upper region 26 is a verysmall portion of the overall heater 24. In other words, the heater 24 ismuch bigger in thickness and volume than the region 26, the region 26only constituting a few surface layers.

As another alternative, the resistance of the region 26 may be increasedby an oxygen plasma treatment. In such case, the arrows A representoxygen plasma which reacts with the heater 24 to form an oxide thereof.That oxide, in the region 26, has higher resistance than the underlyingregion 27 of the heater 24.

In the case of an implant to increase the resistance of the region 26, aseparate anneal step may not be necessary. For example, ensuing stepsthat involve temperature processing of 250° C. may be sufficient toactivate the implanted species.

As shown in FIG. 9, a chalcogenide material 28 is then deposited intothe pore 17 with the heater 24. The memory material 28 acts as the phasechange memory material for the cell. The implantation of FIG. 7 alsoimproves adhesion of dielectric layers, such as spacer 22 and layer 16,to the material 28. The memory material 28 is then planarized as shownin FIG. 10.

In FIG. 11, the ovonic threshold switch 120 (FIG. 1) is then formed overthe memory element 130. An electrode 30 is deposited, followed by thedeposition of a chalcogenide material 32 that does not change phase, inturn followed by an upper electrode 34. The sandwich of the upperelectrode 34, chalcogenide material 32, and lower electrode 30 is thenpatterned as indicated in FIG. 12.

The patterned structure is covered with a passivation layer 18 as shownin FIG. 13. The passivation layer 18 may, for example, be a nitride.Thus, the passivation layer 18 covers the underlying portion of thedielectric 16 and the threshold device 120.

Thereafter, a dielectric 20 is deposited as shown in FIG. 3. Thedielectric 20 is trenched and an upper electrode 36 is formed in thetrench. The upper electrode may act as a column line 141-143 (FIG. 1).

Memory material 28 is a phase change, programmable material capable ofbeing programmed into one of at least two memory states by applying acurrent to memory material 28 to alter the phase of memory material 28between a substantially crystalline state and a substantially amorphousstate, wherein a resistance of memory material 28 in the substantiallyamorphous state is greater than the resistance of memory material 28 inthe substantially crystalline state.

Programming of memory material 28 to alter the state or phase of thematerial is accomplished by applying voltage potentials to theconductors 14 and 36, thereby generating a voltage potential acrossselect device 120 and memory element 130. When the voltage potential isgreater than the threshold voltage of select device 120 and memoryelement 130, then an electrical current flows through memory material 28in response to the applied voltage potential, and results in heating ofmemory material 28.

This heating alters the memory state or phase of memory material 28.Altering the phase or state of memory material 28 alters the electricalcharacteristic of memory material 28, e.g., the resistance of thematerial is altered by altering the phase of the memory material 28.Memory material 28 is referred to as a programmable resistive material.

In the “reset” state, memory material 28 is in an amorphous orsemi-amorphous state and in the “set” state, memory material 28 is in acrystalline or semi-crystalline state. The resistance of memory material28 in the amorphous or semi-amorphous state is greater than theresistance of memory material 28 in the crystalline or semi-crystallinestate. It is to be appreciated that the association of reset and setwith amorphous and crystalline states, respectively, is a convention andthat at least an opposite convention may be adopted.

Using electrical current, memory material 28 is heated to a relativelyhigher temperature to amorphosize memory material 28 and “reset” memorymaterial 28 (e.g., program memory material 28 to a logic “0” value).Heating the volume of memory material 28 to a relatively lowercrystallization temperature crystallizes memory material 28 and “sets”memory material 28 (e.g., program memory material 28 to a logic “1”value). Various resistances of memory material 28 may be achieved tostore information by varying the amount of current flow and durationthrough the volume of memory material 28.

The composition of switching material 32 may comprise a Si concentrationof about 14%, a Te concentration of about 39%, an As concentration ofabout 37%. a Ge concentration of about 9%, and an In concentration ofabout 1%. In another example, the composition of switching material 32may comprise a Si concentration of about 14%, a Te concentration ofabout 39%, an As concentration of about 37%, a Ge concentration of about9%, and a P concentration of about 1%. In these examples, thepercentages are atomic percentages which total 100% of the atoms of theconstituent elements.

In another embodiment, a composition for switching material 32 includesan alloy of arsenic (As), tellurium (Te), sulfur (S), germanium (Ge),selenium (Se), and antimony (Sb) with respective atomic percentages of10%, 21%, 2%, 15%, 50%, and 2%.

In other embodiments, switching material 32 includes Si, Te, As, Ge,sulfur (S). and selenium (Se). As an example, the composition ofswitching material 32 comprises a Si concentration of about 5%, a Teconcentration of about 34%, an As concentration of about 28%, a Geconcentration of about 11%, a S concentration of about 21%, and a Seconcentration of about 1%.

The switching material 32 is a thin film material having a thicknessranging from about 20 A to about 2000 A. In one embodiment, thethickness of the material 32 ranges from about 100 A to about 1000 A. Inanother embodiment, the thickness of the material 32 is about 300 A.

Suitable materials for electrodes 30 and 34 include a thin film oftitanium (Ti), titanium nitride (TiN), titanium tungsten (TiW), carbon(C), silicon carbide (SiC), titanium aluminum nitride (TiAlN), titaniumsilicon nitride (TiSiN), polycrystalline silicon, tantalum nitride(TaN), some combination of these films, or other suitable conductors orresistive conductors compatible with switching material 32.

Turning to FIG. 14, a portion of a system 500 in accordance with anembodiment of the present invention is described. System 500 may be usedin wireless devices such as, for example, a personal digital assistant(PDA), a laptop or portable computer with wireless capability, a webtablet, a wireless telephone, a pager, an instant messaging device, adigital music player, a digital camera, or other devices that may beadapted to transmit and/or receive information wirelessly. System 500may be used in any of the following systems: a wireless local areanetwork (WLAN) system, a wireless personal area network (WPAN) system, acellular network, although the scope of the present invention is notlimited in this respect.

System 500 includes a controller 510, an input/output (I/O) device 520(e.g., a keypad, display), a memory 530, and a wireless interface 540coupled to each other via a bus 550.

Controller 510 may comprise, for example, one or more microprocessors,digital signal processors, microcontrollers, or the like. Memory 530 maybe used to store messages transmitted to or by system 500. Memory 530may also optionally be used to store instructions that are executed bycontroller 510 during the operation of system 500, and may be used tostore user data. Memory 530 may be provided by one or more differenttypes of memory. For example, memory 530 may comprise any type of randomaccess memory, a volatile memory, a non-volatile memory such as a flashmemory and/or a memory 100 discussed herein.

I/O device 520 may be used by a user to generate a message. System 500may use wireless interface 540 to transmit and receive messages to andfrom a wireless communication network with a radio frequency (RF)signal. Examples of wireless interface 540 may include an antenna or awireless transceiver.

In accordance with another embodiment of the present invention, thedielectric region surrounding the heater is treated to improve theadhesion properties thereof.

According to this embodiment, as shown in FIG. 15, a second dielectriclayer 40 is formed over the dielectric layer 16 and the stack of thedielectric layer 16 and the second dielectric layer 40 is etched to forman opening 42 defining a contact opening structure. The remainingstructure of FIG. 15 is similar to the structure previously described inconnection with FIG. 4.

Next, FIG. 16, the opening 42 is covered with a sidewall spacer 45,using known techniques. The spacer 45 is e.g., of nitride.

Then, as shown in FIG. 17, the heater 24 is deposited to completely fillthe remaining opening 42 and to cover the top of the second dielectriclayer 40. This structure is then planarized in a timed polish so as toremove a portion of the second dielectric layer 40, and to polish awaythe flared region 41 (see FIG. 17) of the spacer 45, as shown in FIG.18.

Thereafter, a silicon implant is accomplished as indicated at B in FIG.19. The implant converts the top portion 40 a of the second dielectriclayer 40 to silicon nitride. The implant conditions are the same asthose described previously in connection with FIG. 7.

Silicon-implanted nitride has good adhesion to overlying layersincluding chalcogenide containing layers. Thus, the silicon-implantednitride layer 40 a acts as a glue or adhesion layer.

Moreover, the implanted region 24 b of the heater 24 is converted totitanium silicon nitride, which has higher resistivity than thenon-implanted titanium nitride region 27. Annealed silicon-implantedtitanium nitride, or titanium silicon nitride has a very high adhesionto overlying layers including chalcogenide containing layers.

Thus, a dual resistance heater 24 is formed at the same time that thetop portion 40 a of the second dielectric layer 40 is modified to makeit an effective glue layer. In this embodiment, the top portion 40 a ofthe second dielectric layer 40 is substantially planar. In other words,it does not extend into the opening 42 that includes the heater 24.

Next, as shown in FIG. 20, a chalcogenide layer 46 is deposited,followed by an upper electrode 48. Then, referring to FIG. 21, the upperelectrode 48 and the chalcogenide layer 46 are patterned.

Finally, it is clear that numerous variations and modifications may bemade to method and the contact region, the phase change memory cell andprocess described and illustrated herein, all falling within the scopeof the invention as defined in the attached claims.

All of the above U.S. patents, U.S. patent application publications,U.S. patent applications, foreign patents, foreign patent applicationsand non-patent publications referred to in this specification and/orlisted in the Application Data Sheet, are incorporated herein byreference, in their entirety.

The invention claimed is:
 1. A phase change device comprising: a phasechange material region; and a dual-resistance heater having a firstregion and a second region, the first region of the dual-resistanceheater having a first surface in contact with the phase change materialregion and a second surface in contact with the second region, the firstregion of the dual-resistance heater having a higher resistance than thesecond region of the dual-resistance heater.
 2. The device of claim 1,wherein the first region of the dual-resistance heater has implantedsilicon atoms.
 3. The device of claim 1, wherein the first surface ofthe dual-resistance heater has a higher concentration of oxygen atomsthan the remainder of the dual-resistance heater.
 4. The device of claim1, further including a dielectric layer having a pore therein, thedual-resistance heater being formed in the pore.
 5. The device of claim4, further including a spacer in the pore, the dual-resistance heaterbeing formed within the spacer.
 6. The device of claim 4, wherein thedual-resistance heater completely fills the pore.
 7. The device of claim1, wherein the phase change material region is of a chalcogenidematerial.
 8. The device of claim 4, wherein the phase change materialregion is of a chalcogenide material and extends in the pore in contactwith the dual-resistance heater.
 9. The device of claim 1, wherein thedual-resistance heater includes titanium silicon nitride in the firstsurface.
 10. A system comprising: a controller; a battery coupled to thecontroller; and a phase change device coupled to the controller, thephase change device including a phase change material region and adual-resistance heater, the dual-resistance heater having a first regionand a second region, the first region of the dual-resistance heaterhaving a first surface in contact with the phase change material regionand a second surface in contact with the second region, the first regionof the dual-resistance heater having a higher resistance than the secondregion of the dual-resistance heater.
 11. The system of claim 10 whereinthe first region of the dual-resistance heater includes titanium siliconnitride and the second region of the dual-resistance heater includestitanium nitride.
 12. A method of manufacturing a phase change devicecomprising: forming a resistive material layer in a dielectric layer;the resistive material layer having a top surface region and a bulkregion, the top surface region being substantially coplanar with asurface of the dielectric layer; implanting ions into the surface of thedielectric layer and the top surface region of the resistive materiallayer to form an adhesion layer in the dielectric layer whilesimultaneously increasing the resistance of the top surface region ofthe resistive layer to be a higher resistance than the bulk region, and;forming a phase change material layer overlying the resistive materiallayer and the dielectric layer, the phase change material layer being incontact with the top surface region of the resistive material layer. 13.The method of claim 12 wherein the top surface region is implanted withsilicon.
 14. The method of claim 12 wherein the bulk region of theresistive material is titanium nitride and the top surface region istitanium silicon nitride.
 15. The method of claim 12 wherein the topsurface region is treated with oxygen plasma.
 16. The phase changedevice of claim 1, wherein the first region is smaller than the secondregion of the dual-resistance heater.
 17. The phase change device ofclaim 1, wherein the first region comprises a few surface layers of thedual-resistance heater.